\(n_{H_2SO_4}=\dfrac{200.4,9\%}{98}=0,1\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ a.n_{BaSO_4}=n_{BaCl_2}=n_{H_2SO_4}=0,1\left(mol\right)\\ n_{HCl}=2.0,1=0,2\left(mol\right)\\ C\%_{ddBaCl_2}=\dfrac{0,1.208}{300}.100\approx6,933\%\\ b.m_{ddsau}=200+300-0,1.233=476,7\left(g\right)\\ C\%_{ddHCl}=\dfrac{0,2.36,5}{476,7}.100\approx1,531\%\)

\(a)n_{H_2SO_4}=\dfrac{58,8.20}{100.98}=0,12mol\\ n_{BaCl_2}=\dfrac{200.5,2}{100.208}=0,05mol\\ BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\\ \Rightarrow\dfrac{0,12}{1}>\dfrac{0,05}{2}\Rightarrow H_2SO_4.dư\\ BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)

0,05         0,05             0,05           0,1

\(m_{BaSO_4}=0,05.233=11,65g\\ b)m_{dd}=58,8+200-11,65=247,15g\\ C_{\%HCl}=\dfrac{0,1.36,5}{247,15}\cdot100=1,48\%\\ C_{\%H_2SO_4,dư}=\dfrac{\left(0,12-0,05\right).98}{247,15}\cdot100=2,78\%\)

mình giải ở dưới r nhé. 

Bài 19  :

\(a) n_{Al} = \dfrac{10,8}{27} = 0,4(mol)\\ 2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2\\ n_{H_2} = \dfrac{3}{2}n_{Al} = 0,6(mol)\\ V_{H_2} = 0,6.22,4 = 13,44(lít)\\ b) \text{Chất tan : }Al_2(SO_4)_3\\ n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,2(mol)\\ m_{Al_2(SO_4)_3} = 0,2.342 = 68,4(gam)\)

Bài 18 : 

\(a) n_{HCl} = \dfrac{250.7,3\%}{36,5 } = 0,5(mol)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,25(mol) \Rightarrow V_{H_2} = 0,25.22,4 = 5,6(lít)\\ b) \text{Chất tan : } ZnCl_2\\ n_{ZnCl_2} = n_{H_2} = 0,25(mol)\\ m_{ZnCl_2} = 0,25.136 = 34(gam)\)

\(a,\left\{{}\begin{matrix}m_{BaCl_2}=\dfrac{100\cdot10,4\%}{100\%}=10,4\left(g\right)\\m_{H_2SO_4}=\dfrac{200\cdot9,8\%}{100\%}=19,6\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=\dfrac{10,4}{208}=0,05\left(mol\right)\\n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\end{matrix}\right.\)

\(PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)

Vì \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{2}\) nên \(H_2SO_4\) dư

\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\ \Rightarrow m_{BaSO_4}=0,05\cdot233=11,65\left(g\right)\)

\(b,n_{HCl}=n_{BaSO_4}=0,05\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,05\cdot36,5=1,825\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=100+200-11,65=288,35\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{1,825}{288,35}\cdot100\%\approx0,63\%\)

\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)

\(n_{H_2SO_4}=0.3\cdot1=0.3\left(mol\right)\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(0.1........0.1...........0.1.......0.1\)

\(\Rightarrow H_2SO_4dư\)

\(n_{H_2SO_4\left(dư\right)}=0.3-0.1=0.2\left(mol\right)\)

\(n_{ZnSO_4}=n_{H_2}=0.1\left(mol\right)\)

\(C_{M_{ZnSO_4}}=\dfrac{0.1}{0.3}=0.33\left(M\right)\)

\(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0.2}{0.3}=0.66\left(M\right)\)

\(a) Zn + H_2SO_4 \to ZnSO_4 + H_2\\ b) n_{Zn} = \dfrac{6,5}{65} = 0,1 < n_{H_2SO_4} =0,3 \to H_2SO_4\ dư\\ n_{H_2SO_4\ pư} = n_{ZnSO_4} = n_{Zn} = 0,1(mol)\\ n_{H_2SO_4\ dư} = 0,3 - 0,1 = 0,2(mol)\\ c) C_{M_{ZnSO_4}} = \dfrac{0,1}{0,3} = 0,33M\\ C_{M_{H_2SO_4}} = \dfrac{0,2}{0,3} = 0,67M\)

\(n_{Zn}=\dfrac{m}{M}=0,1\left(mol\right)\)

\(n_{H2SO4}=C_M.V=0,3\left(mol\right)\)

a, \(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

b, Thấy 0,3 > 0,1

=> Sau phản ứng Zn hết, H2SO4 còn dư ( dư 0,3 - 0,1 = 0,2 mol )

- Theo PTHH : \(n_{ZnSO4}=n_{Zn}=0,1\left(mol\right)\)

c, Ta có : \(\left\{{}\begin{matrix}C_{MH2SO4}=\dfrac{n}{V}=\dfrac{2}{3}M\\C_{MZnSO4}=\dfrac{n}{V}=\dfrac{1}{3}M\end{matrix}\right.\)

\(n_{MgO}=\dfrac{2}{40}=0,05\left(mol\right)\)

\(n_{H2SO4}=\dfrac{19,6\%.100}{100\%.98}=0,2\left(mol\right)\)

Pt : \(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

Xét tỉ lệ : \(\dfrac{0,05}{1}< \dfrac{0,2}{1}\Rightarrow H_2SO_4dư\)

Theo pt : \(n_{MgO\left(pư\right)}=n_{MgSO4}=0,05\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgSO4}=\dfrac{0,05.120}{2+100}.100\%=5,88\%\\C\%_{ddH2SO4\left(dư\right)}=\dfrac{\left(0,2-0,05\right).98}{2+100}.100\%=14,41\%\end{matrix}\right.\)

\(n_{BaCl_2}=\dfrac{200.10,4\%}{208}=0,1\left(mol\right)\\ a,BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\\ b,Qu\text{ỳ}-t\text{í}m-ho\text{á}-\text{đ}\text{ỏ}-do-c\text{ó}-\text{ax}it-HCl\\ c,n_{BaSO_4}=n_{H_2SO_4}=n_{BaCl_2}=0,1\left(mol\right)\\ m_{k\text{ết}-t\text{ủa}}=m_{BaSO_4}=233.0,1=23,3\left(g\right)\\ d,m_{\text{dd}H_2SO_4}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\\ e,m_{\text{dd}HCl}=200+200-23,3=376,7\left(g\right)\\ n_{HCl}=0,1.2=0,2\left(mol\right)\\ C\%_{\text{dd}HCl}=\dfrac{0,2.36,5}{376,7}.100\approx1,938\%\)